Tobi Amusan clocked 12.56s in semifinal (Heat 2) to reach her third successive World Championship final.
Title contenders Kendra Harrison, Jasmine Camacho-Quinn and Nia Ali posted a time of 12.33s, 12.41s, and 12.49s respectively.
The women's 100m Hurdles final will hold on Thursday at 8:22pm Nigerian time.
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